The immobilization and electrochemical behaviors of cytochrome c on a NaY zeolite modified electrode were studied. The interaction between cytochrome c and NaY zeolite particles was examined by using UV-Vis spectroscopy and electrochemical methods. The direct electron transfer of the immobilized cytochrome c exhibited a pair of redox peaks with the E1/2 of −(44±3)mV (versus SCE) in 0.1 M pH 7.0...

The surfaces of NaY zeolite particles were modified by the alkylsilylation of n-octadecyltrichlorosilane (OTS). Two kinds of modified NaY zeolites were prepared; one with its external surface partially and the other fully covered with alkylsilyl groups. Since the size of OTS is bigger than the pore diameter of NaY, it is attached on the external surface, leaving the internal pore accessible to ...

A continuous microwave equipment (CME) has been successfully developed in order to achieve an extremely rapid and mass production for ZSM-5 and NaY zeolite. A precursor mixture for synthesis of ZSM-5 was prepared by mixing aluminosilicate gel with a nanoseed solution obtained under microwave irradiation, and pumped continuously into the CME. Duration time in the CME was 5 min to accomplish the ...

This work undertakes the study of the detoxification reactions of O, S-dimethyl phosphoramidithioate (methamidophos) as an organophophorus insecticide on the 14.7 wt% magnetite (Fe3O4) nanoparticles/Ag-NaY faujasite molecular sieve zeolite (FMSZ) composite. The influence of solvent (methanol, acetonitrile and n-hexane) on the detoxification potential of composite was inves...

This work undertakes the study of the detoxification reactions of O, S-dimethyl phosphoramidithioate (methamidophos) as an organophophorus insecticide on the 14.7 wt% magnetite (Fe3O4) nanoparticles/Ag-NaY faujasite molecular sieve zeolite (FMSZ) composite. The influence of solvent (methanol, acetonitrile and n-hexane) on the detoxification potential of composite was inves...

Conversion of glycerol into high yields of 1,2-propanediol in absence of added hydrogen is possible with Pt impregnated NaY zeolite characterized by extra-zeolitic metal particles combined with zeolite Brønsted acidity.

Microwave heating has been shown to influence various inorganic chemical reactions. Substantial reductions in the synthesis time for materials have been reported (1). Additionally, product characteristics and quality of materials synthesized by microwave heating are different from those synthesized under conventional heating methods. The mechanism which results in microwave enhancement is not c...

The electroactivity of zeolite-encapsulated redox-active transition metal complexes, {M(L)}Z, was explored for Co(salen) and [Fe(bpy)3] formed in NaY zeolite (where salen ) N,N′-bis(salicylidene)ethylenediamine and bpy ) 2,2′-bipyridine). The zeolite boundary was characterized via X-ray photoelectron spectroscopy (XPS) and cyclic voltammetry in nonaqueous electrolyte at either zeolite-modified ...

this work undertakes the study of the detoxification reactions of o, s-dimethyl phosphoramidithioate (methamidophos) as an organophophorus insecticide on the 14.7 wt% magnetite (fe3o4) nanoparticles/ag-nay faujasite molecular sieve zeolite (fmsz) composite. the influence of solvent (methanol, acetonitrile and n-hexane) on the detoxification potential of composite was investigated. for this surv...